Details
High Quality Chinese Factory supply 557-36-8 2-IODOOCTANE
- Molecular Formula: C8H17I
- Molecular Weight: 240.127
- Vapor Pressure: 0.285mmHg at 25°C
- Refractive Index: 1.4986 (estimate)
- Boiling Point: 210°C at 760 mmHg
- Flash Point: 74.3°C
- PSA： 0.00000
- Density: 1.335g/cm3
- LogP: 3.78030
2-IODOOCTANE(Cas 557-36-8) Usage
|
Synthesis Reference(s) |
Tetrahedron Letters, 28, p. 4497, 1987 DOI: 10.1016/S0040-4039(00)96546-8 |
|
Safety Profile |
Moderately toxic by ingestion. Aneye irritant. When heated to decomposition it emits toxicvapors of Ií. |
InChI:InChI=1/C8H17I/c1-3-4-5-6-7-8(2)9/h8H,3-7H2,1-2H3
557-36-8 Relevant articles
Iron-Catalyzed Oxyalkylation of Terminal Alkynes with Alkyl Iodides
Deng, Weili,Ye, Changqing,Li, Yajun,Li, Daliang,Bao, Hongli
supporting information, p. 261 - 265 (2019/01/10)
A general oxyalkylation of terminal alky...
Ready access to organoiodides: Practical hydroiodination and double-iodination of carbon-carbon unsaturated bonds with I2
Xiao, Jing,Han, Li-Biao
, p. 3510 - 3515 (2019/05/17)
By using I2 or I2/H3PO3 system, various ...
Method of preparing iodine alkane by using rhodium catalysis
-
Paragraph 0040-0041, (2018/04/03)
The invention relates to the field of or...
Rhodium-Catalyzed Generation of Anhydrous Hydrogen Iodide: An Effective Method for the Preparation of Iodoalkanes
Zeng, Chaoyuan,Shen, Guoli,Yang, Fan,Chen, Jingchao,Zhang, Xuexin,Gu, Cuiping,Zhou, Yongyun,Fan, Baomin
supporting information, p. 6859 - 6862 (2018/10/25)
The preparation of anhydrous hydrogen io...
557-36-8 Process route
-
-
111-66-0,25068-25-1
oct-1-ene
-
-
36049-78-2,557-36-8
2-iodooctane
| Conditions | Yield |
|---|---|
|
With
diphenyl hydrogen phosphite; diphenyl-phosphinic acid; iodine;
In
chloroform;
at 20 - 30 ℃;
for 16h;
regioselective reaction;
Inert atmosphere;
|
98%
|
|
With
polymethylhydrosiloxane; iodine;
In
chloroform;
at 20 ℃;
for 0.333333h;
|
94%
|
|
With
phosphoric acid; iodine;
Inert atmosphere;
Schlenk technique;
Green chemistry;
|
94%
|
|
With
hydrogen iodide;
cetyltributylphosphonium bromide;
at 115 ℃;
for 0.25h;
|
90%
|
|
With
bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; hydrogen; iodine; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl;
In
toluene;
at 20 ℃;
for 36h;
under 30003 Torr;
|
76%
|
|
With
bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; hydrogen; iodine; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl;
In
toluene;
for 32h;
under 1500.15 Torr;
Autoclave;
Schlenk technique;
|
74%
|
|
With
aluminum oxide; iodine;
In
Petroleum ether;
for 2h;
Heating;
|
83 % Chromat.
|
|
With
chloro-trimethyl-silane; water; sodium iodide;
In
acetonitrile;
for 1h;
Ambient temperature;
|
98 % Chromat.
|
|
|
|
|
With
iodine; Diphenylphosphine oxide;
In
chloroform-d1;
at 20 ℃;
for 16h;
regioselective reaction;
Inert atmosphere;
|
91 %Spectr.
|
-
-
4128-31-8,113301-48-7,4128-32-9
rac-octan-2-ol
-
-
36049-78-2,557-36-8
2-iodooctane
| Conditions | Yield |
|---|---|
|
With
4-aminophenyl diphenylphosphinite; iodine;
In
dichloromethane;
at 20 ℃;
for 0.5h;
|
91.8%
|
|
With
iodine;
In
acetonitrile;
at 120 ℃;
for 0.0833333h;
chemoselective reaction;
Microwave irradiation;
|
91%
|
|
With
N-iodosaccharine; triphenylphosphine;
In
dichloromethane;
at 20 ℃;
for 5h;
|
90%
|
|
With
Silphos; iodine;
In
acetonitrile;
for 2h;
Heating;
|
87%
|
|
With
zirconium(IV) chloride; sodium iodide;
In
acetonitrile;
for 2h;
Heating;
|
85%
|
|
With
1H-imidazole; iodine; triphenylphosphine;
In
dichloromethane;
at 0 - 20 ℃;
Inert atmosphere;
Schlenk technique;
|
69%
|
|
With
1H-imidazole; iodine; triphenylphosphine;
In
dichloromethane;
at -10 - 20 ℃;
for 72h;
|
67%
|
|
With
iodophosphorus;
|
|
|
With
N,N'-dicyclohexyl-N-methylcarbodiimidium iodide;
In
tetrahydrofuran;
|
|
|
Multistep reaction;
(i) Me3SiCl, Py, (ii) Me3SiI, CHCl3;
|
|
|
Multistep reaction;
(i) P2I4, CS2, (ii) K2CO3;
|
|
|
With
pyridine; hydrogen fluoride; potassium iodide;
|
|
|
Multistep reaction;
(i) Et3N, 2-fluoro-1-methyl-pyridinium toluene-4-sulfonate, benzene, (ii) NaI, acetone;
|
|
|
With
1-iodo-N,N,2-trimethylprop-1-en-1-amine;
In
dichloromethane;
1.) 0 deg C; 2.) rt., 3h;
|
98 % Spectr.
|
|
With
hydrogen iodide;
at 0 ℃;
|
|
|
With
ziconium(IV) oxychloride octahydrate; sodium iodide;
In
ethanol; water;
at 90 ℃;
for 3h;
|
36 %Chromat.
|
|
Multi-step reaction
with
2
steps
1: pyridine / 20 °C
2: 1-methyl-3-(n-butyl)imidazolium iodide / 24 h / 60 °C / Inert atmosphere; Green chemistry
With
pyridine; 1-methyl-3-(n-butyl)imidazolium iodide;
|
|
|
With
1-iodo-N,N,2-trimethylprop-1-en-1-amine;
In
dichloromethane;
at 20 ℃;
Inert atmosphere;
|
98 %Spectr.
|
|
With
phosphorus pentoxide; potassium iodide;
In
acetonitrile;
at 45 ℃;
for 2h;
|
83 %Chromat.
|
557-36-8 Upstream products
-
4128-31-8
rac-octan-2-ol
-
98-59-9
p-toluenesulfonyl chloride
-
628-61-5
2-chlorooctane
-
557-35-7
2-bromooctane
557-36-8 Downstream products
-
2570-96-9
2-octyl cyanide
-
111-65-9
octane
-
407-95-4
2-fluorooctane
-
111-66-0
oct-1-ene
Related Products
-
2-[[(1,2-benzisothiazol-3-yloxy)methyl]butylamino]ethanolCAS：94087-25-9
-
1-[4-(4-methyl-3-pentenyl)-3-cyclohexen-1-yl]ethan-1-oneCAS：38758-04-2
-
Guanosine-5'-triphosphoric aicd disodium saltCAS：56001-37-7
-
METHYL-BETA-D-ARABINOPYRANOSIDECAS：5328-63-2