Details
Top Quality 1,2-EPOXYTETRADECANE 3234-28-4 Hot Sell In Stock
- Molecular Formula:C14H28 O
- Molecular Weight:212.376
- Vapor Pressure:0.00163mmHg at 25°C
- Melting Point:185-186 °C (decomp)
- Refractive Index:1.4408
- Boiling Point:303.9°Cat760mmHg
- Flash Point:99.3°C
- PSA：12.53000
- Density:0.86g/cm3
- LogP:4.69620
1,2-EPOXYTETRADECANE(Cas 3234-28-4) Usage
|
Air & Water Reactions |
1,2-EPOXYTETRADECANE is sensitive to exposure to moisture. Insoluble in water. |
|
Reactivity Profile |
1,2-EPOXYTETRADECANE, an epoxide, is incompatible with strong acids, caustics, and peroxides. . Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts. |
|
Health Hazard |
ACUTE/CHRONIC HAZARDS: 1,2-EPOXYTETRADECANE is a local irritant. |
|
Fire Hazard |
1,2-EPOXYTETRADECANE is probably combustible. |
|
Flammability and Explosibility |
Nonflammable |
|
General Description |
Clear colorless mobile liquid with an ether-like odor. |
InChI:InChI=1/C14H28O/c1-2-3-4-5-6-7-8-9-10-11-12-14-13-15-14/h14H,2-13H2,1H3
3234-28-4 Relevant articles
Proton Switch in the Secondary Coordination Sphere to Control Catalytic Events at the Metal Center: Biomimetic Oxo Transfer Chemistry of Nickel Amidate Complex
Kim, Soohyung,Jeong, Ha Young,Kim, Seonghan,Kim, Hongsik,Lee, Sojeong,Cho, Jaeheung,Kim, Cheal,Lee, Dongwhan
supporting information, p. 4700 - 4708 (2021/02/12)
High-valent metal-oxo species are key in...
Enantioselective organocatalysis-based synthesis of 3-hydroxy fatty acids and fatty γ-lactones
Bourboula, Asimina,Limnios, Dimitris,Kokotou, Maroula G.,Mountanea, Olga G.,Kokotos, George
, (2019/06/10)
3-Hydroxy fatty acids have attracted the...
Dinuclear Iron(III) and Nickel(II) Complexes Containing N-(2-Pyridylmethyl)-N′-(2-hydroxyethyl)ethylenediamine: Catalytic Oxidation and Magnetic Properties
Jeong, Ah Rim,Shin, Jong Won,Jeong, Jong Hwa,Bok, Kwon Hee,Kim, Cheal,Jeong, Donghyun,Cho, Jaeheung,Hayami, Shinya,Min, Kil Sik
, p. 3023 - 3033 (2017/03/13)
Dinuclear FeIII and NiII complexes, [(ph...
Trinuclear nickel and cobalt complexes containing unsymmetrical tripodal tetradentate ligands: Syntheses, structural, magnetic, and catalytic properties
Shin, Jong Won,Jeong, Ah Rim,Lee, Sun Young,Kim, Cheal,Hayami, Shinya,Min, Kil Sik
, p. 14089 - 14100 (2016/11/06)
The coordination chemistries of the tetr...
3234-28-4 Process route
-
-
1120-36-1
1-tetradecene
-
-
3234-28-4
1,2-epoxytetradecane
| Conditions | Yield |
|---|---|
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 4 ℃;
for 18h;
|
96% |
|
With
Ni(dmp)2; oxygen; isovaleraldehyde;
In
1,2-dichloro-ethane;
for 47h;
under 760 Torr;
Ambient temperature;
|
89% |
|
With
3-chloro-benzenecarboperoxoic acid;
|
87% |
|
With
Ni(N-(2-pyridylmethyl)-N’-(2-hydroxyethyl)ethylenediamine)(N3)2; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane; acetonitrile;
at 20 ℃;
for 0.166667h;
|
43.1% |
|
With
[(N-(2-pyridylmethyl)iminodiethanol)2Co3(CH3COO)4]; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane; acetonitrile;
at 20 ℃;
for 0.166667h;
Catalytic behavior;
|
34.3% |
|
With
[NiII(2-(di(pyridin-2-ylmethyl)amino)-N-(2-(5-methylpyridin-2-yl)phenyl)acetamidate)](ClO4); 3-chloro-benzenecarboperoxoic acid;
In
acetonitrile;
at 25 ℃;
for 0.166667h;
Reagent/catalyst;
|
20.3% |
|
With
oxygen;
bis(acetylacetonato)dioxidomolybdenum(VI);
In
1,2-dichloro-benzene;
at 110 ℃;
for 8.2h;
Further byproducts given. Yields of byproduct given;
|
46.3 % Chromat. |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 25 ℃;
for 48h;
|
87.9 g |
|
With
dihydrogen peroxide; n-tetradecanoic acid;
at 25 ℃;
for 24h;
immobilised Candida antarctica lipase (comp. A and B);
|
85 % Chromat. |
|
With
Sal-Phe-Mn; oxygen;
at 120 ℃;
for 10h;
|
|
|
With
dihydrogen peroxide;
|
|
|
With
Novozym 435; dihydrogen peroxide; carbonic acid dimethyl ester;
at 40 ℃;
for 16h;
|
69 % Chromat. |
|
Multi-step reaction with 2 steps
1.1: potassium ferricyanide; aq. K2CO3; potassium osmate / quinuclidine / 2-methyl-propan-2-ol / 72 h
1.2: 88 percent / aq. sodium sulfite / 2-methyl-propan-2-ol / 2 h
2.1: HBr / acetic acid / 0.5 h
2.2: 93 percent / K2CO3 / methanol / 2 h
With
potassium osmate(VI); hydrogen bromide; potassium carbonate; potassium hexacyanoferrate(III);
Quinuclidine;
In
acetic acid; tert-butyl alcohol;
|
|
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
|
|
|
With
peracetic acid; manganese(II) perchlorate; ammonium bicarbonate;
In
water; acetic acid; acetonitrile;
at 20 ℃;
for 0.666667h;
|
85 %Chromat. |
|
With
peracetic acid; C26H30F6MnN8O8S2;
In
dichloromethane; acetonitrile;
at 0 ℃;
for 0.55h;
|
|
|
With
cobalt(II) perchlorate hexahydrate; 3-chloro-benzenecarboperoxoic acid;
In
acetonitrile;
at 20 ℃;
for 0.166667h;
|
|
|
With
C60H46Co4F10N4O14S2; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane; acetonitrile;
at 20 ℃;
Catalytic behavior;
|
76.4 %Chromat. |
-
-
21129-09-9
tetradecane-1,2-diol
-
-
3234-28-4
1,2-epoxytetradecane
| Conditions | Yield |
|---|---|
|
tetradecane-1,2-diol;
With
hydrogen bromide;
In
acetic acid;
for 0.5h;
With
potassium carbonate;
In
methanol;
for 2h;
|
93% |
3234-28-4 Upstream products
-
79-21-0
peracetic acid
-
1120-36-1
1-tetradecene
-
21129-09-9
tetradecane-1,2-diol
-
112-71-0
1-Bromotetradecane
3234-28-4 Downstream products
-
20184-35-4
1-Chlor-2-<3,5-dinitro-benzoyloxy>-tetradecan
-
74649-89-1
n-Dodecyl-15-crown-5
-
144343-16-8
2-dodecylcyclopropyl phenyl sulfone
-
133617-29-5
2-Phenyltellanyl-tetradecan-1-ol
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